Canon suggests that Dawn accidentally did although, according to this Buffy wiki , there is an alternate interpretation: After "Family", Miss Kitty Fantastico is not mentioned again until the penultimate episode of Season Seven, "End of Days," when Dawn says “Xander, my crossbow is not out here. I told you, I don’t leave crossbows around all willy-nilly… Not since that time with Miss Kitty Fantastico.” This statement implies that the cat died because Dawn carelessly left a crossbow laying around, though one could also infer that Miss Kitty Fantastico walked across the weapon and nearly skewered someone in the house. Either way, the cat is not shown escaping Sunnydale in the series finale, and can confidently be pronounced dead, lost, or given away.
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